Research · NIST AI
Fundamental Studies of the Conformational Phase Behavior of Chain Molecules at Interfaces
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Key facts
- C., "Separations by Shape: Molecular Shape Recognition in Liquid Chromatography," Chromatographia, 85, 299-305 (2022)
- Effects of surface coverage and bonding chemistry," Analytical Chemistry, 77, 7852-7861 (2005)
- Effects of temperature and chain length," Analytical Chemistry, 77, 7862-7871 (2005)
- A., "Order and disorder in alkyl stationary phases," Analytical and Bioanalytical Chemistry, 382, 646-668 (2005)
Summary
Secure.gov websites use HTTPS A lock or https:// means you’ve safely connected to the.gov website. Chain molecules tethered or adsorbed to solid surfaces are at the heart of a wide range of technologies. Conformational details of tethered alkyl chains have also been studied using advanced Monte Carlo simulation techniques that provide the free energy of the system. Representation of octadecyl stationary phase morphology showing an ordered state and a disordered state. Predicting how the conformational phase behavior of tethered chain molecules depends on external variables is challenging.